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The acetic acid present in white vinegar creates an odor that spiders find unpleasant. In addition, it can even burn these pests on contact with the liquid.
Chestnuts and chestnut wood to keep spiders away
If you don’t like spiders but don’t want to harm them, try placing chestnuts or chestnut wood in key locations in your home. Spiders don’t like the smell of chestnuts.